Structureproperty correlations in oxyfluoride glasses have been explored in a series of lead fluoroborate and lead fluorogermanate glasses with nominal compositions (50 x y z)B2O340PbOy(Al2O3)(10 + x)PbF2zREF3 and (50 x y)GeO240PbOy(Al2O3)(10 + x)PbF2zREF3 (x, y = 0, 10, 0 z 0.5, RE = Eu, Yb). Starting from glasses with a fixed PbF2
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